PROCEEDINGS OF THE SHEVCHENKO SCIENTIFIC SOCIETY

Chemical Sciences

Archive / Том LVI 2019

Volodymyr DUTKA1, Galyna MIDYANA2, Olena PAL’CHIKOVA2, Yuriy DUTKA1, Iryna NAGORNYAK1

1Ivan Franko National University of Lviv, Kyryla and Mefodiya Str., 6, 79005 Lviv, Ukraine
2Physical-Chemistry of Combustible Minerals Department of Lytvynenko Institute of Physical-Organic Chemistry and Coal Chemistry

DOI: https://doi.org/10.37827/ntsh.chem.2019.56.089

INFLUENCE OF THE ORGANIC SOLVENTS ON RATE OF OXIDATION OF THE QUINOLINE BY PEROXYDECANIC ACID

The rate oxidation reaction of quinoline with peroxydecanoic acid in warious organic solvents was studed. It has been found effective rate constants (k) and activation energy (Eak) studed process. Between the parameters of the transition state ΔН≠ and ΔЅ≠ is a linear relationships, indication the presence of countervation effect in our series of experiments. The rate of oxidation and activation energy influation of solvatation peroxyacid and quinoline. The reaction medium affects the rate of oxidation. Correlation equations between the rate constants of the reactions in study and the physicochemical parameters of the solvents were proposed. The correlation equation for effective rate constants and the basic physicochemical parameters of solvents at 318 K has the form:
k = 110.5112 – (1164.3052 ± 153.5936)f(n) + (272.4400 ± 32.1756)f(ε) – (0.8108 ± 0.0749)B + (0.2857 ± 0.0425)δ2 + (0.8974 ± 0.1395)Vм;
N = 8; R = 0,9873; S = 3.2368; F= 1.9458.
The polarizability, basicity, electrophilicity and Hilderbrand's function of solvent have effect of oxydation process. The influence of polarization and molar volume on the rate of oxidation of qunoline decay process is negligible. Correlation equations for effective rate constants for other temperatures are similar. The correlation equation for effective energies (Eак) of activation rate and the basic physicochemical parameters of solvents has the form:
Еак = 194.7419 – (375.9562 ± 51.7252)f(n) – (50.2611 ± 21.5278)f(ε) – (2.7926 ± 0.4541)ET + (0.1978 ± 0.0295)δ2 ;
N = 8; R = 0,9514; S = 3.7139; F = 0.8743.
The polarizability, polarization, electrophilicity and Hilderbrand's function of solvent have effect of energy of activation process. Correlation equations for effective rate constants for other temperatures are similar. The proposed correlation equations relate the parameters of the transition state of the oxydation process and the physic-chemical parameters of solvents.

Keywords: quinoline, oxidation reaction, peroxyacids; rate constant, activation energy; correlation equation; effect of solvent.

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How to Cite

Dutka V., Midyana G., Pal’chikova O., Dutka Y., Nagornyak I. INFLUENCE OF THE ORGANIC SOLVENTS ON RATE OF OXIDATION OF THE QUINOLINE BY PEROXYDECANIC ACID Proc. Shevchenko Sci. Soc. Chem. Sci. 2019 Vol. LVI. P. 89-100.

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